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ChemistryThe Matteson homologation, first developed in 1980, elongates carbon chains by insertion into a C−B bond.1 This versatile reaction traditionally requires three steps: carbanion formation, nucleophilic addition to organoboron, and a thermo- or Lewis acid-promoted boronate rearrangement. These processes often demand exacting conditions, including cryogenic temperatures and handling of air- and moisture-sensitive reagents.2,3 Here, we report a Matt…See the Story
Electrochemical Defluorinative Matteson-Type Homologation
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New Brunswick, New Jersey · New BrunswickFor nearly a century, modern physics has remained fragmented between the local realism of General Relativity, the probabilistic uncertainty of Quantum Mechanics, and the cosmological mysteries of Dark Matter and Dark Energy. This paper presents a third unifying path: the Meta-Quantum F...See the Story
